In situlaser raman spectroscopy during sequential oxidizing and reducing conditions for a vanadium-phosphorous-oxide catalyst
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چکیده
منابع مشابه
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Partial Oxidation of n-Butane over a Sol-Gel Prepared Vanadium Phosphorous Oxide
Vanadium phosphorous oxide (VPO) is traditionally manufactured from solid vanadium oxides by synthesizing VOHPO4·0.5H2O (the precursor) followed by in situ activation to produce (VO)2P2O7 (the active phase). This paper discusses an alternative synthesis method based on sol-gel techniques. Vanadium (V) triisopropoxide oxide was reacted with ortho-phosphoric acid in an aprotic solvent. The produc...
متن کاملIdentification, structure, and spectroscopy of neutral vanadium oxide clusters.
Neutral vanadium oxide clusters are studied by photoionization time-of-flight (TOF) mass spectroscopy, electronic spectroscopy, and density functional theory (DFT) calculations. Mass spectra of vanadium oxide clusters are observed by photoionization with lasers of three different wavelengths: 118, 193, and 355 nm. Mechanisms of 118 nm single photon ionization and 193 and 355 nm multiphoton ioni...
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ژورنال
عنوان ژورنال: The Canadian Journal of Chemical Engineering
سال: 1996
ISSN: 0008-4034,1939-019X
DOI: 10.1002/cjce.5450740507